Quoth Primer
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Due to various ways the body protects the brain, there's no way short of drilling through the skull to sample the neurochemistry. (Yet.) If you're curious, 'circle of willis' is a good phrase to start your study with.
If you need an antidepressant to make starting therapy more tolerable or more possible, you still need to get one which is compatible with your personal neurochemistry, and the specific reason you, individually, are depressed.
If you have family members - as in, blood family - who take antidepressants, find out which ones. That increases the chance that they'll get it right first try.
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